Search results for "Gravimetric analysis"
showing 10 items of 264 documents
Systematic Investigation of Resorcin[4]arene-Based Cavitands as Affinity Materials on Quartz Crystal Microbalances.
2017
Resorcin[4]arene cavitands are well-known supramolecular hosts, and their outstanding guest-binding abilities in solution have been studied in detail in recent decades. In a systematic approach, different resorcin[4]arene cavitands and container molecules are characterized as affinity materials for gravimetric sensing using high-fundamental-frequency quartz crystal microbalances. Analysis of their affinity toward a series of various analytes reveals a remarkable dependence of both selectivity and sensitivity on the shape, accessibility, and size of the cavity, along with their supramolecular interactions with the host molecules.
Application of Rigidity-Controlled Supramolecular Affinity Materials for the Gravimetric Detection of Hazardous and Illicit Compounds.
2016
The combination of an (-)-isosteviol-derived building block and 9,9'-spirobifluorene or tetraphenylmethane generated highly potent new affinity materials for the detection of volatile organic compounds (VOCs). Comparison of their affinity behaviour with different core structures showed remarkable influence on selectivity and sensitivity due to structural rigidity and their pre-organization. Their unique supramolecular properties were investigated in an affinity assay using high fundamental frequency quartz crystal microbalances.
Estimating Gravimetric Moisture of Vegetation Using an Attenuation-Based Multi-Sensor Approach
2018
Estimating parameters for global climate models via combined active and passive microwave remote sensing data has been a subject of intensive research in recent years. A variety of retrieval algorithms has been proposed for the estimation of soil moisture, vegetation optical depth and other parameters. A novel attenuation-based retrieval approach is proposed here to globally estimate the gravimetric moisture of vegetation (m g ) and retrieve information about the amount of water [kg] per amount of wet vegetation [kg]. The parameter m g is particularly interesting for agro-ecosystems, to assess the status of growing vegetation. The key feature of the proposed approach is that it relies on mu…
Artificial Oral Processing of Extruded Pea Flour Snacks
2021
International audience; The structure of extruded pea flour can affect chewing performances. Our objective was to relate the bolus properties (fragmentation, moisture content and viscosity) of chewed extruded pea snacks to their structure. In order to have control over oral physiological parameters, we opted for an in vitro approach using a chewing simulator, the variables of which were the flow rate of artificial salivary fluid and chewing time. The structure of the extruded pea snacks was characterized by its density and protein solubility in dithioerythritol (DTE), which reflected the amount of protein aggregates cross-linked by disulphide bonds. The particle size distribution and median…
Conifer Needles as Thermoplastic Composite Fillers: Structure and Properties
2016
This study describes the properties of thermoplastic polymer composites based on polyethylene (of low and high density) and ethylene-propylene copolymers using various types of conifer needles (pine, spruce, fir, and cedar) as fillers. For the needles, thermogravimetric analysis (TGA) and TGA/Fourier transform infrared spectroscopy (TGA/FTIR) were performed to investigate their structures and thermal resistance, as required for the composite processing methods. Moreover, structural differences were studied for the analyzed fillers and composite materials (FTIR). The results were compared with the values obtained for composites with conifer wood flour. Composites with conifer needles (pine) …
Water Structure in Proteins in Solid State Studied by Near Infrared Spectroscopy
2017
Water adsorption in proteins is the crucial process of protein folding and structure stabilizing. Adsorption of water on proteins can be evaluated by near-infrared spectroscopy, a useful technique for observing combination frequency of a water molecule. In this work, albumin, lysozyme, and silk, were used as models for α-helix and β-pleated sheet proteins. Their NIR spectra during water adsorption process were measured by using an NIR spectrometer equipped with a transflectance accessory. Moreover, the quantitative adsorption of water was determined by gravimetric technique. The results indicate that, there are five different NIR absorptions arise from the OH combination frequencies of wate…
Residual water and electrical properties of polyaniline
1994
Summary form only given. The work aims to study the mechanism of interaction between water molecules and polyaniline (PANI) backbone as an important constituent of acid-base transformations ensuring good conductive properties of PANI. Experiments have been made using chemically synthesized emeraldine base subjected to different chemical treatments and aging procedures. Thermogravimetric measurement have shown that water content in polymeric matrices may amount up to 20-25 wt.% with two distinguished reversible absorbance states of water molecules. Weakly bond water (3-5 kcal/mol) is incorporated into PANI from ambient atmosphere and could be eliminated by drying at room temperature in vacuu…
Absorption kinetics and swelling stresses in hydrothermally aged epoxies investigated by photoelastic image analysis
2015
Abstract The present work proposes an experimental optical methodology able to measure the transient swelling stresses induced by the water uptake ageing of polymers. In particular, the work describes the implementation of a Photoelastic technique to quantify internal stresses arising during the hydrothermal ageing of cast epoxy samples. The material investigated is a model DGEBA/DDS epoxy system. Curing and post-curing cycles have been optimised in order to obtain a fully cured, high T g , and completely stress free initial condition. Rectangular beam samples were then left in a hydrothermal bath at 90 °C, and regularly monitored by gravimetric and photoelastic analyses. The quantitative e…
Humidity of Anaesthetic Gases with Respect to Low Flow Anaesthesia
1994
It has been demonstrated in an experimental study in swine using the scanning electron microscope that a rebreathing technique utilising minimal fresh gas flowrates significantly improves climatization of anaesthetic gases. Consequently, effects of various anaesthetic techniques on airway climate must be assessed, which covers the need for suitable measuring devices. Basic principles and methods of humidity measurement in flowing anaesthetic gases include gravimetric hygrometry, dew point hygrometry, wet-dry bulb psychrometry, mass spectrometry, spectroscopic hygrometry and electrical hygrometry. A custom-made apparatus for continuous measurement of humidity and temperature in the inspired…
Synthesis, characterization, and thermal behavior of steroidal dendrons
2004
A series of novel dendritic steroidal polyesters of first and second generation has been synthesized in convergent fashion by the use of 2,2-bis(hydroxymethyl)propionic acid as a repeating unit. The first- and second-generation hydroxy-functionalized dendrons with a variety of surface modifications were produced through the use of four bile acids: lithocholic acid (LCA), ursodeoxycholic acid (UDCA), deoxycholic acid (DCA), and cholic acid (CA). The thermal behavior of the steroidal dendrons was characterized by differential scanning calorimetry (DSC) and by thermogravimetric analysis (TGA). Finally, quantum chemical calculation methods were used to study the geometries of the dendrons and t…